Functionally terminated poly(methyl acrylate) by SET-LRP initiated with CHBr3 and CHI3

被引：88

作者：

Lligadas, Gerard ^{[1
]}

Ladislaw, Janine S. ^{[1
]}

Guliashvili, Tamaz ^{[1
]}

Percec, Virgil ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2008年 / 46卷 / 01期

关键词：

functional chain ends; living polymerization; polyacrylates; radical polymerization; SET-LRP;

D O I：

10.1002/pola.22379

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The single-electron transfer living radical polymerization (SET-LRP) of methyl acrylate initiated with bromoform (CHBr3) and iodoform (CHI3) and catalyzed by Cu(0)/Me-6-TREN in DMSO at 25 degrees C provides a reliable method to prepare poly (methyl acrylate) (PMA) with active chain ends and controlled structure that can undergo subsequent functionalization to provide strategies for the synthesis of different block copolymers and other complex architectures. A detailed kinetic and structural analysis was used to assess the scope and the limitations of CHBr3 and CHI3 as initiators under SET-LRP conditions. (C) 2007 Wiley Periodicals, Inc.

引用

页码：278 / 288

页数：11

共 28 条

[21] Disulfonyl chlorides: A universal class of initiators for metal-catalyzed ''living'' diradical polymerization of styrene(s), methacrylates, and acrylates [J].

Percec, V ;

Kim, HJ ;

Barboiu, B .

MACROMOLECULES, 1997, 30 (21) :6702-6705

[22] Metal-catalyzed ''living'' radical polymerization of styrene initiated with arenesulfonyl chlorides. From heterogeneous to homogeneous catalysis [J].

Percec, V ;

Barboiu, B ;

Neumann, A ;

Ronda, JC ;

Zhao, MY .

MACROMOLECULES, 1996, 29 (10) :3665-3668

[23] Scope and limitations of functional sulfonyl chlorides as initiators for metal-catalyzed "living" radical polymerization of styrene and methacrylates [J].

Percec, V ;

Kim, HJ ;

Barboiu, B .

MACROMOLECULES, 1997, 30 (26) :8526-8528

[24] Arenesulfonyl halides: A universal class of functional initiators for metal-catalyzed "living" radical polymerization of styrene(s), methacrylates, and acrylates [J].

Percec, V ;

Barboiu, B ;

Kim, HJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (02) :305-316

[25]

Percec V, 2000, J POLYM SCI POL CHEM, V38, P4776

[26] Ultrafast synthesis of ultrahigh molar mass polymers by metal-catalyzed living radical polymerization of acrylates, methacrylates, and vinyl chloride mediated by SET at 25 °C [J].

Percec, Virgil ;

Guliashvili, Tamaz ;

Ladislaw, Janine S. ;

Wistrand, Anna ;

Stjerndahl, Anna ;

Sienkowska, Monika J. ;

Monteiro, Michael J. ;

Sahoo, Sangrama .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (43) :14156-14165

[27] A density functional role of ligand on the associated with ATRP theory computational study of the stability of CuI and CuII species and SET-LRP [J].

Rosen, Brad M. ;

Percec, Virgil .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (21) :4950-4964

[28]

TSAREVSKY NV, 2007, ORGANOMET CHEM, V692, P3212

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