Twelve-connected net with face-centered cubic topology:: A coordination polymer based on [Cu12(μ4-SCH3)6]6+ clusters and CN- linkers

被引：217

作者：

Li, D ^{[1
]}

Wu, T

Zhou, XP

Zhou, R

Hitang, XC

机构：

[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China

[2] Shantou Univ, Coll Med, Dept Chem, Shantou 515063, Guangdong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 27期

关键词：

cluster compounds; copper; S ligands; solvothermal synthesis; topological networks;

D O I：

10.1002/anie.200500290

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Globular configuration: a microporous coordination polymer based on a dodecanuclear copper(I) cluster (picture: C black, Cu red, N blue, S yellow) as a twelve-connected node, was synthesized by a simultaneous redox, sulfurization, and self-assembly reaction under solvothermal conditions. The synthesis provides a model reaction to simulate the transformation of inorganic sulfur into organic sulfur. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4175 / 4178

页数：4