Lanthanide(III) complexes with a podand Schiff base containing an N4O3 coordination site

被引：20

作者：

Casellato, U ^{[1
]}

Tamburini, S ^{[1
]}

Tomasin, P ^{[1
]}

Vigato, PA ^{[1
]}

Botta, M ^{[1
]}

机构：

[1] UNIV TURIN,DIPARTIMENTO CHIM INORGAN CHIM FIS & CHIM MAT,I-10125 TURIN,ITALY

来源：

INORGANICA CHIMICA ACTA | 1996年 / 247卷 / 02期

关键词：

lanthanide complexes; Schiff base complexes; crystal structures;

D O I：

10.1016/0020-1693(96)05140-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New lanthanide complexes [Ln(L)(dmf)](2) with a podand Schiff base ligand H(3)L have been prepared by [3 + 1] condensation of 2,6-diformyl-4-chlorophenol and tris-(2-aminoethyl) amine in the presence of Ln(Cl)(3) . nH(2)O (Ln = La, Gd and Dy) and NEt(3). The lanthanide(III) ions coordinate into the inner N4O3 chamber of the ligand bearing three free carbonyl groups which may be involved in further functionalization.

引用

页码：143 / 145

页数：3

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