NEW LIGANDS FOR COMPLEXATION OF LANTHANOIDS - THE SYNTHESIS AND STRUCTURES OF A NONADENTATE SCHIFF-BASE LIGAND (L(1)) AND OF THE COMPLEXES [ML(1)(OH2)](CLO4)(3).3MENO(2) (M=LA, PR) AND [YL(1)](CLO4)(3)CENTER-DOT-3MECN

被引:27
作者
ARCHIBALD, SJ [1 ]
BLAKE, AJ [1 ]
SCHRODER, M [1 ]
WINPENNY, REP [1 ]
机构
[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
关键词
D O I
10.1039/c39940001669
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and structures of a nonadentate Schiff-base ligand L(1), prepared from tris(2-aminoethyl)amine and 2,6-diformyl-4-methylphenol, and of its complexes with M(III) ions (M = La, Pr and Y) are reported; [ML(1)(OH2)](ClO4)(3).3MeNO(2) (M = La, Pr) are ten-coordinate species while [YL(1)](ClO4)(3).3MeCN is nine-coordinate.
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页码:1669 / 1670
页数:2
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