Determination of trimethylsilanol in the environment by LT-GC/ICP-OES and GC-MS

被引：36

作者：

Grumping, R ^{[1
]}

Mikolajczak, D ^{[1
]}

Hirner, AV ^{[1
]}

机构：

[1] Univ Essen Gesamthsch, Inst Environm Analyt Chem, D-45177 Essen, Germany

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1998年 / 361卷 / 02期

关键词：

D O I：

10.1007/s002160050849

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The combination of element-specific investigation by low temperature gas chromatography coupled online with inductively coupled plasma optical emission spectroscopy (LT-GC/ICP-OES) and gas chromatography using mass spectrometry detection (GC-MS), as an additional analytical technique for molecular identification, was employed for the determination of volatile organosilicon species. Gaseous and liquid samples from waste deposit sites, waste composting tanks and sewage-disposal plants were investigated. It was frequently possible to identify the labile silanol compound trimethylsilanol as a dominant silicon species in waste disposal and waste composting gases. The results presented give rise to the assumption that trimethylsilanol is a volatile product of the degradation of organosilicon materials under special environmental conditions.

引用

页码：133 / 139

页数：7

共 33 条

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