Use of a bis-lithium amide base in asymmetric metallation of tricarbonyl(η6-1,3-dihydroisobenzothiophene)chromium(0)

被引：20

作者：

Ariffin, A ^{[1
]}

Blake, AJ ^{[1
]}

Ewin, RA ^{[1
]}

Simpkins, NS ^{[1
]}

机构：

[1] Univ Nottingham, Dept Chem, Nottingham NG7 2RD, England

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 15期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0957-4166(98)00267-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiomerically enriched tricarbonyl(eta(6)-arene)chromium complexes derived from tricarbonyl(eta(6)-1,3-dihydroisobenzothiophene)chromium(0) can be obtained in up to 95% ee by means of an enantioselective metallation reaction using the bis-lithium amide base 8. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2563 / 2566

页数：4

共 13 条

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