Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides

被引：54

作者：

Arisawa, M ^{[1
]}

Ono, T ^{[1
]}

Yamaguchi, M ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 34期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/j.tetlet.2005.06.109

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh3)(4) and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides. (c) 2005 Elsevier Ltd. All rights reserved.

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页码：5669 / 5671

页数：3

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