Rhodium-catalyzed sulfur atom exchange reaction between organic polysulfides and sulfur

被引：34

作者：

Arisawa, M ^{[1
]}

Tanaka, K ^{[1
]}

Yamaguchi, M ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 28期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/j.tetlet.2005.05.024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

RhH(PPh3)(4) and cis-1,2-bis(diphenylphosphino)ethylene (dppv) catalyze the exchange of sulfur atoms between sulfur and organic polysulfides. The exchange of dialkyl trisuffides with sulfur proceeds at a high efficiency within 5 min at room temperature yielding a mixture of organic polysulfides. (c) 2005 Elsevier Ltd. All rights reserved.

引用

收藏

页码：4797 / 4800

页数：4

相关论文

共 31 条

[1] Direct episulfidation of alkenes and allenes with elemental sulfur and thiiranes as sulfur sources, catalyzed by molybdenum oxo complexes [J].

Adam, W ;

Bargon, RM ;

Schenk, WA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (13) :3871-3876

[2] Rhodium-catalyzed synthesis of isothiocyanate from isonitrile and sulfur [J].

Arisawa, M ;

Ashikawa, M ;

Suwa, A ;

Yamaguchi, M .

TETRAHEDRON LETTERS, 2005, 46 (10) :1727-1729

[3] Rhodium-catalyzed disulfide exchange reaction [J].

Arisawa, M ;

Yamaguchi, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (22) :6624-6625

[4] Rhodium-catalyzed regio- and stereoselective 1-seleno-2-thiolation of 1-alkynes [J].

Arisawa, M ;

Kozuki, Y ;

Yamaguchi, M .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (23) :8964-8967

[5] Transition metal-catalyzed synthesis of (E)-2-(Alkylthio)alka-1,3-dienes from allenes and dialkyl disulfides with concomitant hydride transfer [J].

Arisawa, M ;

Suwa, A ;

Fujimoto, K ;

Yamaguchi, M .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (05) :560-563

[6] Addition reaction of dialkyl disulfides to terminal alkynes catalyzed by a rhodium complex and trifluoromethanesulfonic acid [J].

Arisawa, M ;

Yamaguchi, M .

ORGANIC LETTERS, 2001, 3 (05) :763-764

[7] SULFURATION OF THE NORBORNENE DOUBLE-BOND [J].

BARTLETT, PD ;

GHOSH, T .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (22) :4937-4943

[8] REACTIONS OF ELEMENTAL SULFUR .2. THE REACTION OF ALKALI CYANIDES WITH SULFUR, AND SOME SINGLE-SULFUR TRANSFER REACTIONS [J].

BARTLETT, PD ;

DAVIS, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (10) :2513-2516

[9] The enthalpy of insertion of sulfur into the metal-hydrogen bond.: Synthetic, structural, and calorimetric study of the complexes HS-M(CO)3C5R5 [M = Cr, Mo, W; R = H, Me] [J].

Bauer, A ;

Capps, KB ;

Wixmerten, B ;

Abboud, KA ;

Hoff, CD .

INORGANIC CHEMISTRY, 1999, 38 (09) :2136-2142

[10] SYNTHESIS, STRUCTURE, AND PROPERTIES OF PENTATHIEPINS [J].

CHENARD, BL ;

HARLOW, RL ;

JOHNSON, AL ;

VLADUCHICK, SA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3871-3879

← 1 2 3 4 →