Supercapacitors utilising ionic liquids

被引:239
作者
Eftekhari, Ali [1 ,2 ]
机构
[1] Ulster Univ, Engn Res Inst, Newtownabbey BT37 OQB, North Ireland
[2] Queens Univ Belfast, Sch Chem & Chem Engn, Stranmillis Rd, Belfast BT9 5AG, Antrim, North Ireland
关键词
Ionic liquids; Polymerised ionic liquids; Supercapacitor; Pseudocapacitance; Gel polymer electrolyte; Porous carbon; ELECTRICAL DOUBLE-LAYER; SOLID-STATE SUPERCAPACITORS; GEL POLYMER ELECTROLYTE; GRAPHENE-BASED SUPERCAPACITORS; HIGH-POWER DENSITY; HIGH-PERFORMANCE SUPERCAPACITORS; ELECTROCHEMICAL ENERGY-STORAGE; ALUMINUM CURRENT COLLECTORS; SURFACE FUNCTIONAL-GROUPS; CARBON-FIBER PAPER;
D O I
10.1016/j.ensm.2017.06.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
Ionic liquids (ILs) can provide a broad range of opportunities for fabricating high-energy supercapacitors owing to their wide stable potential windows, flexibility in design, and ionic properties. Although their applicability had not been fully understood due to an impression that ILs are simply alternative electrolytes in the electrochemical systems, only a fraction of research works is currently focused on pure IL electrolytes, as the emerging attentions are towards new possibilities introduced by ILs. This review provides an overview of different roles of ILs in the development of new supercapacitors and attempts to link these works for a better understanding of the IL potentials and challenges. While manipulating the IL electrolytes can pave the path for the fabrication of practical supercapacitors, gel polymer electrolytes might have a better fortune in the commercial development of flexible devices. In addition to different roles of ILs as the electrolyte components, they can also modify the electrode material to enhance the supercapacitor performance.
引用
收藏
页码:47 / 69
页数:23
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