meso-Aryl Triphyrin(2.1.1)

被引:61
作者
Anju, K. S. [2 ]
Ramakrishnan, S. [2 ]
Srinivasan, A. [1 ]
机构
[1] NISER, Sch Chem Sci, Bhubaneswar 751005, Orissa, India
[2] Natl Inst Interdisciplinary Sci & Technol, NIIST CSIR, Chem Sci & Technol Div, Photosci & Photon Sect, Thiruvananthapuram 695019, Kerala, India
关键词
PORPHYRIN-FORMING REACTIONS; ONE-FLASK SYNTHESES; N-FUSED PORPHYRIN; BINUCLEAR SUBPHTHALOCYANINE; MESOSUBSTITUTED PORPHYRINS; SUBSTITUTED SUBPORPHYRINS; CONTRACTED PORPHYRINS; ABSORPTION; BORON; COMPLEXES;
D O I
10.1021/ol200668a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Synthesis, spectral, and single-crystal X-ray structural analysis of meso-aryl triphyrin(2.1.1) featuring three pyrrole rings and four meso-aryl rings are described. The title compound represents the first example of a ring-contracted meso-aryl beta-unsubstituted free-base triphyrin containing only pyrrole rings reported to date and generates 2-D supramolecular assembly In the solid state.
引用
收藏
页码:2498 / 2501
页数:4
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