Cavity ringdown spectroscopy of molecular ions: A (2)Pi(u)<-X (2)Sigma(g)(+) (6-0) transition of N-2(+)

被引：38

作者：

Kotterer, M

Conceicao, J

Maier, JP

机构：

[1] Inst. für Physikalische Chemie, Universität Basel, CH-4056 Basel

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 259卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(96)00734-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cavity ringdown spectroscopy is combined with a hollow cathode source for the absorption spectroscopy of molecular ions. The A(2) Pi(u) <-- X(2) Sigma(g)(+) (6-0) transition of N-2(+), oscillator strength 9 X 10(-6), could be detected with an ion column density of 10(16) cm(-2). Liquid nitrogen cooling of the plasma results in rotational temperatures of 150-200 K.

引用

页码：233 / 236

页数：4

共 20 条

[1] HIGH-RESOLUTION INFRARED-SPECTROSCOPY OF MOLECULAR-IONS
AMANO, T
[J]. PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1988, 324 (1578): : 163 - 178
[2] ROTATIONAL ANALYSIS OF THE (6,3) VIBRATIONAL BAND OF THE ALPHA(2)PI(4)-CHI(2)SIGMA(+)(G) SYSTEM OF N-2(+) USING VELOCITY MODULATION AND A TI-SAPPHIRE LASER
BACHIR, IH
HUET, TR
DESTOMBES, JL
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1995, 170 (02) : 601 - 603
[3] HIGH-RESOLUTION INFRARED FOURIER-TRANSFORM EMISSION-SPECTRA OF THE N-14(2)+ MEINEL SYSTEM - A2-PI-U-X2-SIGMA-G+
FERGUSON, DW
RAO, KN
MARTIN, PA
GUELACHVILI, G
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1992, 153 (1-2) : 599 - 609
[4] THEORY OF HOLLOW-CATHODE ARC
FERREIRA, CM
DELCROIX, JL
[J]. JOURNAL OF APPLIED PHYSICS, 1978, 49 (04) : 2380 - 2395
[5] A deperturbation analysis of the B-3 Sigma(-)(u)(v'=0-6) and the B''(3)Pi(u)(v'=2-12) states of S-2
Green, ME
Western, CM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (03) : 848 - 864
[6] NEAR-INFRARED DIODE-LASER ABSORPTION-SPECTROSCOPY OF THE (2,0) BAND OF THE ALPHA-2-PI-U-CHI-2-SIGMA-G+ SYSTEM OF THE N-2+ ION GENERATED IN A SUPERSONIC JET EXPANSION
HARADA, K
TANAKA, T
[J]. CHEMICAL PHYSICS LETTERS, 1994, 227 (06) : 651 - 655
[7] Huber KP, 1979, MOL SPECTRA MOL STRU, DOI [10.1007/978-1-4757-0961-2_2, DOI 10.1007/978-1-4757-0961-2_2]
[8] LOFTHUS A, 1977, J PHYS CHEM REF DATA, V6, P284
[9] COHERENT CAVITY RING DOWN SPECTROSCOPY
MEIJER, G
BOOGAARTS, MGH
JONGMA, RT
PARKER, DH
WODTKE, AM
[J]. CHEMICAL PHYSICS LETTERS, 1994, 217 (1-2) : 112 - 116
[10] NESBITT DJ, 1994, ANNU REV PHYS CHEM, V45, P367

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