Extended framework materials incorporating cyanide cluster complexes: structure of the first 3D architecture accommodating organic molecules

被引：85

作者：

Naumov, NG

Soldatov, DV

Ripmeester, JA ^{[2
]}

Artemkina, SB

Fedorov, VE

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Natl Res Council Canada, Steacie Inst Mol Sci, 100 Sussex Dr, Ottawa, ON K1A 0R6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 06期

关键词：

D O I：

10.1039/b008040n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexadentate cluster anions [Re6S8(CN)(6)](4-) coordinate to Mn(ii) centers to give a neutral 3D coordination network topologically related to the structure of Prussian Blue; the residual space is filled with isopropyl alcohol molecules, both ligated to Mn(ii) and guest-solvated.

引用

页码：571 / +

页数：2

共 29 条

[1] THE ARCHETYPE FOR A NEW CLASS OF SIMPLE EXTENDED 3D HONEYCOMB FRAMEWORKS - THE SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF CD(CN)5/3(OH)1/3.1/3(C6H12N4), CD(CN)2.1/3(C6H12N4), AND CD(CN)2.2/3H2O.TBUOH (C6H12N4 = HEXAMETHYLENETETRAMINE) REVEALING 2 TOPOLOGICALLY EQUIVALENT BUT GEOMETRICALLY DIFFERENT FRAMEWORKS [J].