Silicon compounds with strong intramolecular steric interactions. 77. Addition reactions of maleic anhydride to a disilene and a tetrasilabuta-1,3-diene: Formation of bi- and tetracyclic compounds

被引：14

作者：

Boomgaarden, S

Saak, W

Weidenbruch, M

Marsmann, H

机构：

[1] Carl von Ossietzky Univ Oldenburg, Fachbereich Chem, D-26111 Oldenburg, Germany

[2] Univ Gesamthsch Paderborn, Fachbereich Chem, D-33095 Paderborn, Germany

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 12期

关键词：

Addition reactions - Chemical bonds - Crystal structure - Derivatives - Molecular structure - Nuclear magnetic resonance spectroscopy - Structure (composition) - X ray crystallography;

D O I：

10.1021/om010182l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of hexakis(2,4,6-triisopropylphenyl)tetrasilabutadiene with maleic anhydride (3) furnishes the 2,9-dioxa-5,6,7,8-tetrasilatetracyclodecan-3-one derivative 4, presumably by a sequence of two consecutive [2 + 2] cycloadditions. Tetrakis(2,4,6-triisopropylphenyl)disilene reacts with 3 to afford the bicyclic 1,2-dihydrofuro[3,2-d][1,2,3]oxadisilol-5(6H)-one derivative 5 via a formal [2 + 3] cycloaddition and a 1,2-hydrogen shift. The structures of 4 and 5 were determined by X-ray crystallography.

引用

页码：2451 / 2453

页数：3

共 14 条

[1]

Boomgaarden S, 2001, Z ANORG ALLG CHEM, V627, P349, DOI 10.1002/1521-3749(200103)627:3<349::AID-ZAAC349>3.0.CO

[2]

2-R

[3]

BOOMGAARDEN S, IN PRESS Z ANORG ALL

[4] A stable bicyclic compound with two Si=Si double bonds [J].