SOLUTION AND SOLID-STATE OXIDATION CHEMISTRY OF TETRAKIS(2,4,6-TRIISOPROPYLPHENYL)DISILENE

被引：45

作者：

MILLEVOLTE, AJ ^{[1
]}

POWELL, DR ^{[1
]}

JOHNSON, SG ^{[1
]}

WEST, R ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 03期

关键词：

D O I：

10.1021/om00039a014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The air oxidation of tetrakis(2,4,6-triisopropylphenyl)disilene (1) has been investigated. In benzene solution the first oxidation product is the 1,2-disiladioxetane 2, which rearranges to give the 1,3-cyclodisiloxane 3 in addition to a compound with the 1-oxa-2-silacyclopent-3-ene structure (4). The same products are obtained when solid 1 is oxidized. Conditions for the rearrangement of 2 which provide either 3 or 4 pure are also described. Oxidation of 1 with 1 equiv of m-chloroperbenzoic acid produces the disilaoxirane 5 and, with excess oxidant, 3. The X-ray crystal structures of 3 and 5 are reported.

引用

收藏

页码：1091 / 1095

页数：5

相关论文

共 15 条

[1] STEREOCHEMISTRY OF THE ADDITION OF DIARYLSILYLENES TO CIS-2-BUTENES AND TRANS-2-BUTENES [J].

ANDO, W ;

FUJITA, M ;

YOSHIDA, H ;

SEKIGUCHI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (10) :3310-3311

[2] REACTIONS OF TETRAMESITYLDISILENE WITH AZIDES - SYNTHESIS OF DISILAAZIRIDINES [J].

GILLETTE, GR ;

WEST, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 394 (1-3) :45-55

[3] 1,1,2,2-TETRAKIS(2,6-DIMETHYLPHENYL)-1,2-DISILACYCLOPROPANE [J].

MASAMUNE, S ;

MURAKAMI, S ;

TOBITA, H ;

WILLIAMS, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (26) :7776-7778

[4] OXYGENATION OF DIGERMENE DERIVATIVES [J].

MASAMUNE, S ;

BATCHELLER, SA ;

PARK, J ;

DAVIS, WM ;

YAMASHITA, O ;

OHTA, Y ;

KABE, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) :1888-1889

[5]

MCKILLOP K, UNPUB

[6] FORMATION OF A DISILOXIRANE IN THE OXIDATION OF 1,2-DIMESITYL-1,2-DI-TERT-BUTYLDISILAETHYLENE [J].

MICHALCZYK, MJ ;

WEST, R ;

MICHL, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (22) :1525-1526

[7] STRUCTURAL AND CHEMICAL-PROPERTIES OF 1,3-CYCLODISILOXANES [J].

MICHALCZYK, MJ ;

FINK, MJ ;

HALLER, KJ ;

WEST, R ;

MICHL, J .

ORGANOMETALLICS, 1986, 5 (03) :531-538

[8] LOCKED ARYL ROTATION IN CIS-DIARYLACENAPHTHENES, TORSIONALLY RIGID ANALOGS OF CIS-1,2-DIARYLCYCLOPENTANES [J].

MILLER, AR ;

CURTIN, DY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (07) :1860-1865

[9] DISILASELENIRANE AND DISILATELLURIRANE - SYNTHESIS AND CRYSTAL-STRUCTURES [J].

TAN, RPK ;

GILLETTE, GR ;

POWELL, DR ;

WEST, R .

ORGANOMETALLICS, 1991, 10 (03) :546-551

[10] THE 1ST PREPARATION OF DISILENE VIA REDUCTIVE DEHALOGENATION OF 1,2-DICHLORODISILANE - THE FORMATION OF AN UNUSUAL AIR-OXIDATION PRODUCT, 1-OXA-2-SILACYCLOPENT-3-ENE DERIVATIVE [J].

WATANABE, H ;

TAKEUCHI, K ;

NAKAJIMA, K ;

NAGAI, Y ;

GOTO, M .

CHEMISTRY LETTERS, 1988, (08) :1343-1346