SOLUTION AND SOLID-STATE OXIDATION CHEMISTRY OF TETRAKIS(2,4,6-TRIISOPROPYLPHENYL)DISILENE

被引：45

作者：

MILLEVOLTE, AJ ^{[1
]}

POWELL, DR ^{[1
]}

JOHNSON, SG ^{[1
]}

WEST, R ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 03期

关键词：

D O I：

10.1021/om00039a014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The air oxidation of tetrakis(2,4,6-triisopropylphenyl)disilene (1) has been investigated. In benzene solution the first oxidation product is the 1,2-disiladioxetane 2, which rearranges to give the 1,3-cyclodisiloxane 3 in addition to a compound with the 1-oxa-2-silacyclopent-3-ene structure (4). The same products are obtained when solid 1 is oxidized. Conditions for the rearrangement of 2 which provide either 3 or 4 pure are also described. Oxidation of 1 with 1 equiv of m-chloroperbenzoic acid produces the disilaoxirane 5 and, with excess oxidant, 3. The X-ray crystal structures of 3 and 5 are reported.

引用

页码：1091 / 1095

页数：5

共 15 条

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