Total syntheses of (±)-phycocyanobilin and its derivatives bearing a photoreactive group at D-ring

被引：25

作者：

Kakiuchi, T ^{[1
]}

Kato, H ^{[1
]}

Jayasundera, KP ^{[1
]}

Higashi, T ^{[1
]}

Watabe, K ^{[1
]}

Sawamoto, D ^{[1
]}

Kinoshita, H ^{[1
]}

Inomata, K ^{[1
]}

机构：

[1] Kanazawa Univ, Fac Sci, Dept Chem, Kanazawa, Ishikawa 9201192, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 10期

关键词：

D O I：

10.1246/cl.1998.1001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(+/-)-Phycocyanobilin and its derivatives bearing a photoreactive group at D-ring were first synthesized by the development of a new and conveniens method for the preparation of A-ring, transesterification for propanoic acid side-schains of the pyrrole derivative common to B- and C-rings, and deprotection of allyl ester side-chains with a palladium catalyst to avoid migration of exocyclic olefin of A-ring.

引用

页码：1001 / 1002

页数：2

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