Molecular recognition in homogeneous transition metal catalysis: a biomimetic strategy for high selectivity

被引：89

作者：

Das, Siddartha ^{[1
]}

Brudvig, Gary W. ^{[1
]}

Crabtree, Robert H. ^{[1
]}

机构：

[1] Yale Univ, New Haven, CT 06520 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 04期

关键词：

D O I：

10.1039/b710355g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Traditional methods for selectivity control in homogeneous transition metal catalysis either employ steric effects in a binding pocket or chelate control. In a supramolecular strategy, encapsulation of the substrate can provide useful shape and size selectivity. A fully developed molecular recognition strategy involving hydrogen bonding or solvophobic forces has given almost completely regioselective functionalization of remote, unactivated C-H bonds.

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页码：413 / 424

页数：12

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