Isolation and characterization of two guanidines from Galega orientalis Lam cv Gale (fodder galega)

被引:14
作者
Benn, MH
Shustov, G
Shustova, L
Majak, W
Bai, YL
Fairey, NA
机构
[1] UNIV CALGARY,DEPT CHEM,CALGARY,AB T2N 1N4,CANADA
[2] AGR & AGRI FOOD CANADA,RANGE RES STN,KAMLOOPS,BC V2B 8A9,CANADA
[3] AGR & AGRI FOOD CANADA,NO AGR RES CTR,BEAVERLODGE,AB T0H 0C0,CANADA
关键词
Galega orientalis; fodder galega; guanidines; smirnovine; (Z)-4-hydroxysmirnovine;
D O I
10.1021/jf960175l
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
The vegetative parts of Galega orientalis Lam. cv. Gale, being tested in Canada as a new cold-hardy fodder crop, were found to contain two hemiterpenoid guanidines: the know alkaloid smirnovine, and its previously unknown (Z)-4-hydroxy derivative. The synthesis of smirnovine picrate is also described for the first time. A sample of G. orientalis from Estonia yielded smirnovine in similar concentrations (0.2%). Although these levels are low, more research is required to confirm that the alkaloids in fodder galega do not pose a threat to livestock in Canada.
引用
收藏
页码:2779 / 2781
页数:3
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