Radial description of excitation processes of molecular and atomic species in a high-pressure helium microwave plasma torch

被引:23
作者
Alvarez, R [1 ]
Quintero, MC [1 ]
Rodero, A [1 ]
机构
[1] Univ Cordoba, Dept Phys, E-14071 Cordoba, Spain
关键词
D O I
10.1088/0022-3727/38/20/003
中图分类号
O59 [应用物理学];
学科分类号
摘要
In this paper, the radial distributions of emissivity of the species present in the helium-nitrogen, helium-oxygen and helium-argon plasmas sustained by the axial injection torch at atmospheric pressure are studied by optical emission spectroscopy using the Abel inversion procedure. The spectrum was scanned for atomic and ionic lines together with rotational bands of neutral and ionic molecules of such species. The variation of the emissivity with different mixture composition was also studied. No emission from oxygen molecular species (O-2, O-2(+)) was found in the discharge or from the atomic ions N+ or O+. The interaction processes between helium and the introduced species are discussed. A decrease in helium emissivity when compared with the pure helium plasma was found for every plasma gas mixture composition.
引用
收藏
页码:3768 / 3777
页数:10
相关论文
共 25 条
[1]   An Abel inversion method for radially resolved measurements in the axial injection torch [J].
Alvarez, R ;
Rodero, A ;
Quintero, MC .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2002, 57 (11) :1665-1680
[2]  
ALVAREZ R, 2001, P 15 INT S PLASM CHE, P1417
[3]  
ALVAREZ R, 2004, UNPUB J APPL PHYS
[4]  
[Anonymous], 2013, PLASMA KINETICS ATMO
[5]   EVALUATION OF A MICROWAVE-INDUCED PLASMA IN HELIUM AT ATMOSPHERIC-PRESSURE AS AN ELEMENT-SELECTIVE DETECTOR FOR GAS-CHROMATOGRAPHY [J].
BEENAKKER, CIM .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1977, 32 (3-4) :173-187
[6]   Characterization of helium/argon working gas systems in a radiofrequency glow discharge atomic emission source. Part II: Langmuir probe and emission intensity studies for Al, Cu and Macor samples [J].
Belkin, M ;
Caruso, JA ;
Christopher, SJ ;
Marcus, RK .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1998, 53 (6-8) :1197-1208
[7]   CHARGE-TRANSFER IN ANALYTICAL HELIUM PLASMAS [J].
BRANDL, PG ;
CARNAHAN, JW .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1994, 49 (01) :105-115
[8]   Characterization of helium/argon working gas systems in a radiofrequency glow discharge atomic emission source. Part I: Optical emission, sputtering and electrical characteristics [J].
Christopher, SJ ;
Hartenstein, ML ;
Marcus, RK ;
Belkin, M ;
Caruso, JA .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1998, 53 (6-8) :1181-1196
[9]   SPECTRA EXCITED IN HELIUM AFTERGLOW [J].
COLLINS, CB ;
ROBERTSON, WW .
JOURNAL OF CHEMICAL PHYSICS, 1964, 40 (03) :701-&
[10]   The influence of nitrogen entrainment on argon plasmas created by the 'Torche a Injection Axiale' (TIA) [J].
Jonkers, J ;
Hartgers, A ;
Selen, LJM ;
van der Mullen, JAM ;
Schram, DC .
PLASMA SOURCES SCIENCE & TECHNOLOGY, 1999, 8 (01) :49-57