Thermochemistry of oxygen atom transfer from Cp*ReO3

被引：22

作者：

Gable, KP ^{[1
]}

Juliette, JJJ ^{[1
]}

Li, CB ^{[1
]}

Nolan, SP ^{[1
]}

机构：

[1] UNIV NEW ORLEANS, NEW ORLEANS, LA 70148 USA

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 24期

关键词：

D O I：

10.1021/om960238p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction enthalpy for O atom transfer from Cp*ReO3 to PPh(3) in toluene solution is measured to be -28.4 +/- 0.3 kcal/mol and -28.0 +/- 0.6 kcal/mol in THF solution. This allows the strength of the Re=O bond in Cp*ReO3 (in solution) to be estimated at 116.8 +/- 1.2 kcal/mol.

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收藏

页码：5250 / 5251

页数：2

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