Olefin/paraffin separation using membrane based facilitated transport/chemical absorption techniques

被引：145

作者：

Faiz, Rami ^{[1
]}

Li, Kang ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn & Chem Technol, London SW7 2AZ, England

来源：

CHEMICAL ENGINEERING SCIENCE | 2012年 / 73卷

基金：

英国工程与自然科学研究理事会;

关键词：

Olefin/paraffin separation; Facilitated transport; Liquid membranes; Hollow fiber membrane contactors; Membrane electrolytes; Ionic liquid membranes; POLYMER ELECTROLYTE MEMBRANES; SUPPORTED LIQUID-MEMBRANES; TEMPERATURE IONIC LIQUID; SILVER NANOPARTICLES; OLEFIN TRANSPORT; POLY(ETHYLENE OXIDE); COMPLEX MEMBRANES; GAS SEPARATIONS; ETHYLENE/ETHANE SEPARATION; PROPYLENE/PROPANE MIXTURES;

D O I：

10.1016/j.ces.2012.01.037

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Seeking alternative olefin/paraffin separation techniques have been attracting great interest due to the high operating and capital costs of current commercially practiced separation processes. An olefin/paraffin separation scheme using membrane based facilitated transport/chemical absorption techniques offers great advantages such as reducing the operating and capital costs, as well as eliminating the operating drawbacks occurring in absorption processes such as flooding, foam formation, etc. Consequently, the utilization of a facilitated transport/chemical absorption scheme with a suitable membrane system for olefin/paraffin separation would be an attractive option for the replacement of the current separation technologies. A comprehensive review is presented for application of membranes for light olefin/paraffin separation. This article covers all types of membrane based facilitated transport/chemical absorption techniques which include various conventional liquid membranes configurations, membrane contactors and more advanced solid membrane electrolytes. The performance evaluation, shortcomings, and advantages are discussed in details. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：261 / 284

页数：24

共 132 条

[61] Silver polymer electrolytes by π-complexation of silver ions with polymer containing C=C bond and their application to facilitated olefin transport membranes [J].