Concurrent anion•••π interactions between a perchlorate ion and two π-acidic aromatic rings, namely pentafluorophenol and 1,3,5-triazine

被引:76
作者
Goetz, Rens J. [1 ]
Robertazzi, Arturo [2 ,3 ]
Mutikainen, Ilpo [4 ]
Turpeinen, Urho [4 ]
Gamez, Patrick [1 ]
Reedijk, Jan [1 ]
机构
[1] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands
[2] Scuola Int Super Studi Avanzati, Trieste, Italy
[3] CNR, INFM, Democritos Natl Simulat Ctr, Trieste, Italy
[4] Univ Helsinki, Dept Chem, Inorgan Chem Lab, FIN-00014 Helsinki, Finland
关键词
D O I
10.1039/b803817a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The rational design of a ligand containing two electron-poor pi-rings, i.e. a triazine and a pentafluorophenoxy groups, has allowed the preparation of a copper complex where both the anticipated anion center dot center dot center dot pi interactions are present.
引用
收藏
页码:3384 / 3386
页数:3
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