Base-free mizoroki-heck reaction catalyzed by rhodium complexes

被引：55

作者：

Martinez, Remi ^{[1
]}

Voica, Florina ^{[1
]}

Genet, Jean-Pierre ^{[1
]}

Darses, Sylvain ^{[1
]}

机构：

[1] Ecole Natl Super Chim Paris, CNRS, UMR 7573, Lab Synth Select Organ, F-75231 Paris, France

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 17期

关键词：

ARYLBORONIC ACIDS; COUPLING REACTIONS; EFFICIENT ACCESS; BORONIC ACIDS; ASYMMETRIC 1,4-ADDITIONS; PD(II) CATALYSIS; BOND FORMATION; ARYL; ARYLATION; ALKENES;

D O I：

10.1021/ol071098q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A base-free rhodium-catalyzed Mizoroki-Heck (M-H) reaction using potassium aryltrifluoroborates as the arylating agent of alkenes and acetone as a green '' oxidant '' is described. Thanks to the ready availability of organoboranes, this reaction should constitute an interesting alternative to conventional M-H reactions using aryl halides.

引用

页码：3213 / 3216

页数：4

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