Fluorination of B10H102- with an N-fluoro reagent. A new way to transform B-H bonds into B-F bonds

被引：44

作者：

Ivanov, SV

Ivanova, SM

Miller, SM

Anderson, OP

Solntsev, KA

Strauss, SH

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

[2] RUSSIAN ACAD SCI,INST GEN & INORGAN CHEM,MOSCOW 117907,RUSSIA

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 24期

关键词：

D O I：

10.1021/ic961043c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cs2B10H10 reacted with 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (F-TEDA) to form the first fluorinated derivatives of B10H102-, including 1-B10H9F2-, 2-B10H9F2-, 1,10-B10H8F22-, and 1,2,10-B10H7F3-. The B-11 NMR spectra of B10H102- and 1,10-B10H8F22-, both of which have C-4v symmetry, are displayed here.

引用

页码：6914 / &

页数：3