Manganese oxide/MWNTs composite electrodes for supercapacitors

被引:208
作者
Wang, GX [1 ]
Zhang, BL [1 ]
Yu, ZL [1 ]
Qu, MZ [1 ]
机构
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Grad Sch, Chengdu 610041, Peoples R China
关键词
manganese oxide; carbon nanotubes; composite electrode; supercapacitors;
D O I
10.1016/j.ssi.2005.02.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Manganese oxide/multiwalled carbon nanotubes (MWNTs) composite was prepared by mixing manganese oxide and MWNTs through a means of ultrasonic vibration in ethanol solution. A nonaqueous hybrid supercapacitor using manganese oxide/MWNTs (M/M) composite and MWNTs as positive and negative electrodes, respectively, has been designed and investigated by constant current charge/discharge tests. The asymmetric hybrid capacitor has better capacitance and energy characteristics than those of the symmetric ones based on individual M/M composite and MWNTs electrodes. The energy density of the hybrid capacitor can reach 32.91 W h/kg even at a current density of 10 mA/cm cm(2) in 1.0 M LiClO4 electrolyte, which is comparable to that of a manganese oxide/activated carbon hybrid capacitor. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1169 / 1174
页数:6
相关论文
共 26 条
  • [1] An asymmetric hybrid nonaqueous energy storage cell
    Amatucci, GG
    Badway, F
    Du Pasquier, A
    Zheng, T
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (08) : A930 - A939
  • [2] Enhanced supercapacitance of multiwalled carbon nanotubes functionalized with ruthenium oxide
    Arabale, G
    Wagh, D
    Kulkarni, M
    Mulla, IS
    Vernekar, SP
    Vijayamohanan, K
    Rao, AM
    [J]. CHEMICAL PHYSICS LETTERS, 2003, 376 (1-2) : 207 - 213
  • [3] Carbon nanotubes - the route toward applications
    Baughman, RH
    Zakhidov, AA
    de Heer, WA
    [J]. SCIENCE, 2002, 297 (5582) : 787 - 792
  • [4] A hybrid activated carbon-manganese dioxide capacitor using a mild aqueous electrolyte
    Brousse, T
    Toupin, M
    Bélanger, D
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (04) : A614 - A622
  • [5] Manganese oxide/carbon composite electrodes for electrochemical capacitors
    Chang, JK
    Lin, CT
    Tsai, WT
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (07) : 666 - 671
  • [6] Conway B. E., 1999, ELECTROCHEMICAL SUPE, DOI DOI 10.1007/978-1-4757-3058-6
  • [7] Carbon materials for the electrochemical storage of energy in capacitors
    Frackowiak, E
    Béguin, F
    [J]. CARBON, 2001, 39 (06) : 937 - 950
  • [8] IMPROVED CAPACITY RETENTION IN RECHARGEABLE 4V LITHIUM LITHIUM MANGANESE OXIDE (SPINEL) CELLS
    GUMMOW, RJ
    DEKOCK, A
    THACKERAY, MM
    [J]. SOLID STATE IONICS, 1994, 69 (01) : 59 - 67
  • [9] Electrochemical characterization of carbon nanotube/nanohoneycomb diamond composite electrodes for a hybrid anode of Li-ion battery and super capacitor
    Honda, K
    Yoshimura, M
    Kawakita, K
    Fujishima, A
    Sakamoto, Y
    Yasui, K
    Nishio, N
    Masuda, H
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (04) : A532 - A541
  • [10] Use of KCl aqueous electrolyte for 2 V manganese oxide/activated carbon hybrid capacitor
    Hong, MS
    Lee, SH
    Kim, SW
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2002, 5 (10) : A227 - A230