On the stereoselection of iodolactonizations of 3-silyloxyalk-5-enoic acids

被引：12

作者：

Bedford, SB

Fenton, G

Knight, DW

Shaw, DE

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

[2] RHONE POULENC RORER LTD,CENT RES,DAGENHAM RM10 7XS,ESSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 13期

关键词：

D O I：

10.1039/p19960001505

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iodolactonizations of 3-triisopropylsilyloxyalk-5-enoic acids (10b and 12) proceed by way of common transition-state geometry 23, in which the silyloxy group is positioned axially, presumably due to hydrogen bonding with the carboxylic acid group.

引用

页码：1505 / 1509

页数：5

共 15 条

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