Copper hexacyanoferrate with a well-defined open framework as a positive electrode for aqueous zinc ion batteries

被引：255

作者：

Jia, Zhijun ^{[1
,2
]}

Wang, Baoguo ^{[2
]}

Wang, Yi ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China

[2] Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2015年 / 149卷

关键词：

Inorganic compounds; Chemical synthesis; Electron microscopy; Electrochemical properties; X-ray photoemission spectroscopy; PRUSSIAN BLUE; INSERTION PROPERTIES; ENERGY-STORAGE; SODIUM; LITHIUM; NICKEL; OXIDE; FLUOROPHOSPHATE; BEHAVIOR; FILM;

D O I：

10.1016/j.matchemphys.2014.11.014

中图分类号：

T [工业技术];

学科分类号：

120111 [工业工程];

摘要：

The feasibility of the electrochemical zinc ion insertion/extraction reaction in CuHCF nano-cube in aqueous solution is investigated. It is demonstrated for the first time that the divalent zinc ions can be reversibly inserted/extracted into/from CuHCF nano-cube in aqueous solution due to the small radius steric effect of zinc ions. The zinc ion insertion and extraction is controlled by the solid phase diffusion into/from the CuHCF electrode. Divalent cation (de)intercalation discovered in this work expands perspectives on intercalation electrochemistry Of divalent cations, and it will possibly lead to development of novel divalent cation intercalation compounds for aqueous rechargeable batteries. (C) 2014 Elsevier B.V. All rights reserved.

引用

收藏

页码：601 / 606

页数：6

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