Progress in rechargeable magnesium battery technology

被引：491

作者：

Aurbach, Doron ^{[1
]}

Suresh, Gurukar Shivappa ^{[1
]}

Levi, Elena ^{[1
]}

Mitelman, Ariel ^{[1
]}

Mizrahi, Oren ^{[1
]}

Chusid, Orit ^{[1
]}

Brunelli, Michela ^{[2
]}

机构：

[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel

[2] ESRF, F-38043 Grenoble, France

来源：

ADVANCED MATERIALS | 2007年 / 19卷 / 23期

关键词：

D O I：

10.1002/adma.200701495

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new generation of rechargeable magnesium batteries with improved performance is presented. The cathodes are Chevrel phases of the Mo6S8-ySey (y = 0, 1, 2) type. The partial substitution of S by Se in these materials enables a very fast and reversible Mg intercalation at capacities close to the theoretical values, due to structural changes in the Mg insertion sites and increase in the polarizability of the anionic framework of the host. New electrolyte solutions with electrochemical windows wider than 3 V are also briefly reported.

引用

页码：4260 / +

页数：9

共 22 条

[1] Prototype systems for rechargeable magnesium batteries
Aurbach, D
Lu, Z
Schechter, A
Gofer, Y
Gizbar, H
Turgeman, R
Cohen, Y
Moshkovich, M
Levi, E
[J]. NATURE, 2000, 407 (6805) : 724 - 727
[2] Nonaqueous magnesium electrochemistry and its application in secondary batteries
Aurbach, D
Weissman, I
Gofer, Y
Levi, E
[J]. CHEMICAL RECORD, 2003, 3 (01) : 61 - 73
[3] AURBACH D, IN PRESS J POWER SOU
[4] Review on electrode-electrolyte solution interactions, related to cathode materials for Li-ion batteries
Aurbach, Doron
Markovsky, Boris
Salitra, Gregory
Markevich, Elena
Talyossef, Yossi
Koltypin, Maxim
Nazar, Linda
Ellis, Brian
Kovacheva, Daniella
[J]. JOURNAL OF POWER SOURCES, 2007, 165 (02) : 491 - 499
[5] First example of molybdenum atoms in the network of high temperature Chevrel phases:: Moy[Mo6Se8-xSx]
Belin, S
Chevrel, R
Sergent, M
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1999, 145 (01) : 159 - 166
[6] STUDIES OF THE MECHANISM OF THIOPHENE HYDRODESULFURIZATION - H-2 NMR AND MASS-SPECTRAL ANALYSIS OF 1,3-BUTADIENE PRODUCED IN THE DEUTERODESULFURIZATION (DDS) OF THIOPHENE OVER PBMO6S8 CATALYST
BENSON, JW
SCHRADER, GL
ANGELICI, RJ
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 96 (03) : 283 - 299
[7] Solid-state rechargeable magnesium batteries
Chusid, O
Gofer, Y
Gizbar, H
Vestfrid, Y
Levi, E
Aurbach, D
Riech, I
[J]. ADVANCED MATERIALS, 2003, 15 (7-8) : 627 - 630
[8] FISHER O, 1982, TOPICS CURRENT PHYS
[9] Alkyl group transmetalation reactions in electrolytic solutions studied by multinuclear NMR
Gizbar, H
Vestfrid, Y
Chusid, O
Gofer, Y
Gottlieb, HE
Marks, V
Aurbach, D
[J]. ORGANOMETALLICS, 2004, 23 (16) : 3826 - 3831
[10] JONSON DC, 1983, J INORG CHEM, V22, P3773

← 1 2 3 →