Metal-containing molecular rectangles: synthesis and photophysical properties

被引:182
作者
Thanasekaran, P
Liao, RT
Liu, YH
Rajendran, T
Rajagopal, S [1 ]
Lu, KL
机构
[1] Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India
[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan
关键词
molecular rectangles; molecular boxes; self-assembly; transition metals; luminescence; molecular recognition;
D O I
10.1016/j.ccr.2004.11.006
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This article reviews recent progress in our understanding of molecular rectangles and rectangular boxes. The synthesis of macrocycles that contain nitrogen-, oxygen-, sulphur- and phosphorus-bridged ligands is described. Synthetic routes for the preparation of the metallomacromolecules including stepwise and self-assembly strategies as well as their photophysical and molecular recognition properties are discussed. Preliminary applications of such compounds as chemical sensing devices are also briefly reviewed. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1085 / 1110
页数:26
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