Metal-containing molecular rectangles: synthesis and photophysical properties

被引：182

作者：

Thanasekaran, P

Liao, RT

Liu, YH

Rajendran, T

Rajagopal, S ^{[1
]}

Lu, KL

机构：

[1] Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India

[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 9-10期

关键词：

molecular rectangles; molecular boxes; self-assembly; transition metals; luminescence; molecular recognition;

D O I：

10.1016/j.ccr.2004.11.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article reviews recent progress in our understanding of molecular rectangles and rectangular boxes. The synthesis of macrocycles that contain nitrogen-, oxygen-, sulphur- and phosphorus-bridged ligands is described. Synthetic routes for the preparation of the metallomacromolecules including stepwise and self-assembly strategies as well as their photophysical and molecular recognition properties are discussed. Preliminary applications of such compounds as chemical sensing devices are also briefly reviewed. (c) 2004 Elsevier B.V. All rights reserved.

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页码：1085 / 1110

页数：26

相关论文

共 115 条

[61]

LEHN JM, 1988, ANGEW CHEM INT EDIT, V27, P90

[62] Self-assembly of discrete cyclic nanostructures mediated by transition metals [J].

Leininger, S ;

Olenyuk, B ;

Stang, PJ .

CHEMICAL REVIEWS, 2000, 100 (03) :853-907

[63] Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J].

Li, H ;

Eddaoudi, M ;

O'Keeffe, M ;

Yaghi, OM .

NATURE, 1999, 402 (6759) :276-279

[64]

Lindner E, 2003, EUR J INORG CHEM, P705

[65] KINETIC EVIDENCE FOR THE FORMATION OF DISCRETE 1,4-DEHYDROBENZENE INTERMEDIATES - TRAPPING BY INTERMOLECULAR AND INTRAMOLECULAR HYDROGEN-ATOM TRANSFER AND OBSERVATION OF HIGH-TEMPERATURE CIDNP [J].

LOCKHART, TP ;

COMITA, PB ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (14) :4082-4090

[66] Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole [J].

Luo, JD ;

Xie, ZL ;

Lam, JWY ;

Cheng, L ;

Chen, HY ;

Qiu, CF ;

Kwok, HS ;

Zhan, XW ;

Liu, YQ ;

Zhu, DB ;

Tang, BZ .

CHEMICAL COMMUNICATIONS, 2001, (18) :1740-1741

[67] Taking advantage of right angles in N1,N7-diplatinated purine nucleobases: Toward molecular squares, rectangles, and meanders [J].

Luth, MS ;

Freisinger, E ;

Glahe, F ;

Muller, J ;

Lippert, B .

INORGANIC CHEMISTRY, 1998, 37 (13) :3195-3203

[68] Self-assembly of octarhenium-based neutral luminescent rectangular prisms [J].

Manimaran, B ;

Thanasekaran, P ;

Rajendran, T ;

Liao, RT ;

Liu, YH ;

Lee, GH ;

Peng, SM ;

Rajagopal, S ;

Lu, KL .

INORGANIC CHEMISTRY, 2003, 42 (16) :4795-4797

[69] Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles [J].

Manimaran, B ;

Thanasekaran, P ;

Rajendran, T ;

Lin, RJ ;

Chang, IJ ;

Lee, GH ;

Peng, SM ;

Rajagopal, S ;

Lu, KL .

INORGANIC CHEMISTRY, 2002, 41 (21) :5323-5325

[70] Novel one-pot synthesis of luminescent neutral rhenium-based molecular rectangles [J].

Manimaran, B ;

Rajendran, T ;

Lu, YL ;

Lee, GH ;

Peng, SM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (05) :515-517

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