Self-assembly of octarhenium-based neutral luminescent rectangular prisms

被引：46

作者：

Manimaran, B

Thanasekaran, P

Rajendran, T

Liao, RT

Liu, YH

Lee, GH

Peng, SM

Rajagopal, S

Lu, KL ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 107, Taiwan

[3] Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 16期

关键词：

D O I：

10.1021/ic034172j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Self-assembly of rhenium-based nanoscale rectangular prismatic boxes has been achieved in quantitative conversion. The facrhenium corner provided three mutually perpendicular coordination sites and served as a good candidate for the construction of 3-D boxes. These are the first Re-based, neutral, luminescent prisms of M8L2L'(8) type that has been characterized crystallographically. Their luminescent properties and molecular recognition capabilities make these molecular prisms interesting supramolecules.

引用

页码：4795 / 4797

页数：3

共 25 条

[1] DINUCLEATING, TRINUCLEATING, AND TETRANUCLEATING PYRIDYL LIGANDS WHICH FACILITATE MULTICENTER MAGNETIC EXCHANGE BETWEEN PARAMAGNETIC MOLYBDENUM CENTERS [J].