Self-assembly with postmodification: Kinetically stabilized metalla-supramolecular rectangles

被引：180

作者：

Kuehl, CJ ^{[1
]}

Huang, SD

Stang, PJ

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

[2] Kent State Univ, Dept Chem, Kent, OH 44242 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2001年 / 123卷 / 39期

关键词：

D O I：

10.1021/ja0114355

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Interaction of a predesigned molecular "clip" (4) with rigid dipyridyl bridging ligands, in acetone/ water mixtures, leads to the formation of molecular rectangles (5-8) in 92-97% isolated yields via spontaneous self-assembly. Characterization was accomplished with multinuclear NMR and UV-vis spectroscopy, FAB mass spectrometry, and X-ray crystallography. The length of these metallamacrocycles ranges from 2 to 3 nm. Postmodification via non-nucleophilic counterion exchange results in enhanced structural integrity for the assemblies.

引用

收藏

页码：9634 / 9641

页数：8

相关论文

共 102 条

[1] Addition-elimination equilibria involving 16e(-) platinum(O) and 18e(-) platinum(II) complexes [J].

Albano, VG ;

Castellari, C ;

Monari, M ;

DeFelice, V ;

Panunzi, A ;

Ruffo, F .

ORGANOMETALLICS, 1996, 15 (19) :4012-4019

[2] SYNTHESIS AND CHARACTERIZATION OF 5-COORDINATE [PTCL(L)(N-N)(OLEFIN)]+ COMPLEXES - MOLECULAR-STRUCTURE OF [PTCL(PYRIDINE)(2,9-DIMETHYL-1,10-PHENANTHROLINE)(ETHYLENE)]-(CF3SO3) [J].

ALBANO, VG ;

CASTELLARI, C ;

MONARI, M ;

DEFELICE, V ;

PANUNZI, A ;

RUFFO, F .

ORGANOMETALLICS, 1992, 11 (11) :3665-3669

[3] Synthesis of five-coordinate Pt(II) complexes containing organogermanium fragments in axial position.: Structure of [PtCl(GePh2Cl)(2,9-Me2-1,10-phen)(CH2=CH2)] [J].

Albano, VG ;

Ferrara, ML ;

Monari, M ;

Panunzi, A ;

Ruffo, F .

INORGANICA CHIMICA ACTA, 1999, 285 (01) :70-75

[4] ATROPISOMERISM IN ASYMMETRIC CIS-DIPHOSPHINE ARYLPLATINUM COMPLEXES [J].

ALCOCK, NW ;

BROWN, JM ;

PEREZTORRENTE, JJ .

TETRAHEDRON LETTERS, 1992, 33 (03) :389-392

[5] Neutral anion receptors: design and application [J].

Antonisse, MMG ;

Reinhoudt, DN .

CHEMICAL COMMUNICATIONS, 1998, (04) :443-448

[6]

Atwood J, 1990, INCLUSION PHENOMENON

[7] STRUCTURES OF TRANS-BIS[(PHENYLAZO)ACETALDOXIMATO]PLATINUM(II) AND TRANS-PALLADIUM(II) - A CASE OF NONPLANAR TETRACOORDINATION IN A BIS COMPLEX OF PALLADIUM(II) [J].

BANDYOPADHYAY, D ;

BANDYOPADHYAY, P ;

CHAKRAVORTY, A ;

COTTON, FA ;

FALVELLO, LR .

INORGANIC CHEMISTRY, 1984, 23 (12) :1785-1787

[8] MULTICOMPONENT SELF-ASSEMBLY - SPONTANEOUS FORMATION OF A CYLINDRICAL COMPLEX FROM 5 LIGANDS AND 6 METAL-IONS [J].

BAXTER, P ;

LEHN, JM ;

DECIAN, A ;

FISCHER, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (01) :69-72

[9]

Baxter P. N. W., 1996, COMPREHENSIVE SUPRAM, V9, P165

[10]

Baxter PNW, 1999, CHEM-EUR J, V5, P102

← 1 2 3 4 5 6 7 8 9 10 →