Ruthenium(II)-catalyzed asymmetric transfer hydrogenation of ketones using chiral oxazolinylferrocenylphosphines and one of their Ru(II) complex

被引：56

作者：

Arikawa, Y

Ueoka, M

Matoba, K

Nishibayashi, Y

Hidai, M

Uemura, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

[2] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 572卷 / 02期

关键词：

transfer hydrogenation; oxazolinylferrocenylphosphine; ruthenium(II) complex; crystal structure;

D O I：

10.1016/S0022-328X(98)00948-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral oxazolinylferrocenylphosphines act as efficient ligands for Ru(II)-catalyzed asymmetric transfer hydrogenation of a variety of alkyl aryl ketones and alkyl methyl ketones to give the corresponding alcohols in moderate yield with moderate-to-good enantiomeric excess. A new ruthenium(II) complex containing a chiral oxazolinylferrocenylphosphine has been prepared and fully characterized by X-ray crystallography, the complex being revealed to work as a catalyst for this hydrogenation as well. 1999 Elsevier Science S.A. All rights reserved.

引用

页码：163 / 168

页数：6

共 14 条

[1]

ARIKAWA Y, 1997, 72 ANN M CHEM SOC JA, P810

[2] Synthesis and characterization of ruthenium(II) complexes containing chiral bis(ferrocenyl)-P-3 or -P2S ligands. Asymmetric transfer hydrogenation of acetophenone [J].