Molecular recognition of long dicarboxylate/dicarboxylic species via supramolecular/coordinative interactions with ditopic receptors.: Crystal structure of {[Cu2L(H2O)2]⊃pimelate}(ClO4)2

被引:55
作者
Bazzicalupi, C
Bencini, A
Bianchi, A
Fusi, V
Garcia-España, E
Giorgi, C
Llinares, JM
Ramirez, JA
Valtancoli, B
机构
[1] Univ Florence, Dept Chem, I-50144 Florence, Italy
[2] Univ Urbino, Inst Chem Sci, I-61029 Urbino, Italy
[3] Univ Valencia, Dept Inorgan Chem, E-46100 Valencia, Spain
关键词
D O I
10.1021/ic9812151
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Molecular recognition of pimelate, hydrogen pimelate, and pimelic acid has been achieved in different and contiguous pH ranges via supramolecular and/or coordinative interactions with a macrocyclic ditopic polyazacyclophane and its mono- and dinuclear Cu-II complexes.
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页码:620 / +
页数:3
相关论文
共 12 条
[1]   CAMBRIDGE CRYSTALLOGRAPHIC DATA CENTER - COMPUTER-BASED SEARCH, RETRIEVAL, ANALYSIS AND DISPLAY OF INFORMATION [J].
ALLEN, FH ;
BELLARD, S ;
BRICE, MD ;
CARTWRIGHT, BA ;
DOUBLEDAY, A ;
HIGGS, H ;
HUMMELINK, T ;
HUMMELINKPETERS, BG ;
KENNARD, O ;
MOTHERWELL, WDS ;
RODGERS, JR ;
WATSON, DG .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (OCT) :2331-2339
[2]  
[Anonymous], 1997, SUPRAMOLECULAR CHEM
[3]   Laying traps for elusive prey: Recent advances in the non-covalent binding of anions [J].
Atwood, JL ;
Holman, KT ;
Steed, JW .
CHEMICAL COMMUNICATIONS, 1996, (12) :1401-1407
[4]   Mono- and bi-nuclear copper(II) complexes with polyazacyclophane receptors containing two different binding sites [J].
Bazzicalupi, C ;
Bencini, A ;
Bianchi, A ;
Fusi, V ;
Giorgi, C ;
Paoletti, P ;
Valtancoli, B .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (19) :3535-3541
[5]  
BEER PD, 1992, SUPRAMOLECULAR CHEM
[6]   Investigation of equilibria in solution. Determination of equilibrium constants with the HYPERQUAD suite of programs [J].
Gans, P ;
Sabatini, A ;
Vacca, A .
TALANTA, 1996, 43 (10) :1739-1753
[7]   ANION RECEPTOR MOLECULES - CHAIN-LENGTH DEPENDENT SELECTIVE BINDING OF ORGANIC AND BIOLOGICAL DICARBOXYLATE ANIONS BY DITOPIC POLYAMMONIUM MACROCYCLES [J].
HOSSEINI, MW ;
LEHN, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (12) :3525-3527
[8]  
JOHNSON CK, 1973, 5138 ORNL
[9]  
KATZ HE, 1991, INCLUSION COMPOUNDS
[10]  
Lehn J. M., 1995, SUPRAMOLECULAR CHEM