Molecular recognition of long dicarboxylate/dicarboxylic species via supramolecular/coordinative interactions with ditopic receptors.: Crystal structure of {[Cu2L(H2O)2]⊃pimelate}(ClO4)2

被引:55
作者
Bazzicalupi, C
Bencini, A
Bianchi, A
Fusi, V
Garcia-España, E
Giorgi, C
Llinares, JM
Ramirez, JA
Valtancoli, B
机构
[1] Univ Florence, Dept Chem, I-50144 Florence, Italy
[2] Univ Urbino, Inst Chem Sci, I-61029 Urbino, Italy
[3] Univ Valencia, Dept Inorgan Chem, E-46100 Valencia, Spain
关键词
D O I
10.1021/ic9812151
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Molecular recognition of pimelate, hydrogen pimelate, and pimelic acid has been achieved in different and contiguous pH ranges via supramolecular and/or coordinative interactions with a macrocyclic ditopic polyazacyclophane and its mono- and dinuclear Cu-II complexes.
引用
收藏
页码:620 / +
页数:3
相关论文
共 12 条
[11]  
SHELDRICK GM, 1993, SHELXL93 PROGRAM REF
[12]   AN EMPIRICAL-METHOD FOR CORRECTING DIFFRACTOMETER DATA FOR ABSORPTION EFFECTS [J].
WALKER, N ;
STUART, D .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (JAN) :158-166