Harnessing the potential of N-heterocyclic carbenes for the rejuvenation of group-transfer polymerization of (meth)acrylics

被引：114

作者：

Raynaud, Jean ^{[1
]}

Ciolino, Andres ^{[2
]}

Baceiredo, Antoine ^{[3
]}

Destarac, Mathias ^{[3
]}

Bonnette, Fabien ^{[3
]}

Kato, Tsuyoshi ^{[3
]}

Gnanou, Yves ^{[1
]}

Taton, Daniel ^{[1
]}

机构：

[1] Univ Bordeaux 1, ENSCPB, CNRS, LCPO, F-330607 Pessac 9, France

[2] Univ Nacl Sur, Consejo Nacl Invest Cient & Tecn, PLAPIQUI, RA-8000 Bahia Blanca, Buenos Aires, Argentina

[3] Univ Toulouse 3, LHFA, F-31062 Toulouse 9, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 29期

关键词：

block copolymers; carbenes; organocatalysis; polymerization;

D O I：

10.1002/anie.200800490

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Neutral but versatile: N-heterocyclic carbenes are very efficient catalysts for the group-transfer polymerization of acrylates and methacrylates in both polar and apolar media. These organocatalysts were also used to design all-(meth)acrylic di-and triblock copolymers. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5390 / 5393

页数：4

共 47 条

[41] Cyanosilylation of aldehydes catalyzed by N-heterocyclic carbenes [J].