Complexes of heteroscorpionate trispyrazolylborate ligands.: Part XI.: Weak CH/π interactions in crystals of hydrotris(3-phenylpyrazolyl) boratothallium(I) and hydrobis(5-methyl-3-phenylpyrazolyl)(3,5-dimethylpyrazol-yl)boratothallium(I) studied by X-ray crystallography

被引：32

作者：

Ciunik, Z

Ruman, T

Lukasiewicz, M

Wolowiec, S

机构：

[1] Rzeszow Univ Technol, Fac Chem, PL-35959 Rzeszow, Poland

[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 690卷 / 1-3期

关键词：

trispyrazolylboratothallium complexes; structures; CH/pi interaction;

D O I：

10.1016/j.molstruc.2003.12.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thallium(I) complexes of heteroscorpionate hydrobis(3-phenyl-5-methylpyrazolyl)(3,5-dimethylpyrazol-yl)borate and hydrotris(3-phenylpyrazol-1-yl)borate were studied crystallographically. Both ligands were coordinated in kappa(3) fashion via N-2 atoms of pyrazol-1-yl moieties. Both compounds crystallize as centrosymmetric dimers in which weak CH/pi intra- and interdimer interactions are responsible for arrangement in crystal structure. (C) 2003 Elsevier B.V. All fights reserved.

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页码：175 / 180

页数：6

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