Growth and electronic transport in 9,10-diphenylanthracene single crystals - An organic semiconductor of high electron and hole mobility

被引:65
作者
Tripathi, Ashutosh Kumar
Heinrich, Michael
Siegrist, Theo
Pflaum, Jens
机构
[1] Univ Stuttgart, Inst Phys 3, D-70550 Stuttgart, Germany
[2] Bell Labs, Murray Hill, NJ 07974 USA
关键词
D O I
10.1002/adma.200602162
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electron and hole transport is demonstrated on bulk crystals of the organic serniconductor 9,10-diphenylanthracene (DPA). The high mobilities at room E 2 temperature for electrons (ca. 13 cm(2) Vs(-1)) and holes (ca. 3.7 cm(2) VS-1) make DPA a prominent candidate for device E 6 applications. The hole mobility follows a bandlike transport at high temperatures (200K-400K) and a saturation behavior in the low-temperature regime (see figure), the latter being discussed in the context of various transport models.
引用
收藏
页码:2097 / +
页数:6
相关论文
共 20 条
[1]   Organic single-crystal field-effect transistors [J].
de Boer, RWI ;
Gershenson, ME ;
Morpurgo, AF ;
Podzorov, V .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2004, 201 (06) :1302-1331
[2]   Space charge limited transport and time of flight measurements in tetracene single crystals: A comparative study [J].
de Boer, RWI ;
Jochemsen, M ;
Klapwijk, TM ;
Morpurgo, AF ;
Niemax, J ;
Tripathi, AK ;
Pflaum, J .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (03) :1196-1202
[3]   TRAPPING OF PHOTOCARRIERS IN ANTHRACENE BY ANTHRAQUINONE, ANTHRONE AND NAPHTHACENE [J].
HOESTEREY, DC ;
LETSON, GM .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1963, 24 (12) :1609-&
[4]   Effect of impurities on the mobility of single crystal pentacene [J].
Jurchescu, OD ;
Baas, J ;
Palstra, TTM .
APPLIED PHYSICS LETTERS, 2004, 84 (16) :3061-3063
[5]   GENERATION AND TRANSPORT OF CHARGE-CARRIERS IN CHARGE-TRANSFER COMPLEX "ANTHRACENE-PYROMELLITIC-DIANHYDRIDE [J].
KARL, N ;
ZIEGLER, J .
CHEMICAL PHYSICS LETTERS, 1975, 32 (03) :438-442
[6]   Electron and hole mobilities in high purity anthracene single crystals [J].
Karl, N ;
Marktanner, J .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2001, 355 :149-173
[7]  
KARL N, 1980, CRYSTALS GROWTH PROP, P77
[8]   CRYSTAL-STRUCTURE OF 9,10-DIPHENYLANTHRACENE, (C6H5)(C14H8)(C6H5) [J].
LANGER, V ;
BECKER, HD .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1992, 199 (3-4) :313-315
[9]   ON THE PRODUCTION OF SINGLE CRYSTALS OF NAPHTHALENE AND ANTHRACENE [J].
LIPSETT, FR .
CANADIAN JOURNAL OF PHYSICS, 1957, 35 (03) :284-298
[10]   Description of vapour pressures of polycyclic aromatic compounds by graph theoretical indices [J].
Niederfellner, J ;
Lenoir, D ;
Matuschek, G ;
Rehfeldt, F ;
Utschick, H ;
Bruggemann, R .
QUANTITATIVE STRUCTURE-ACTIVITY RELATIONSHIPS, 1997, 16 (01) :38-48