Hydrosilylation of aldehydes and ketones catalyzed by [Ph3P(CuH)]6

被引：83

作者：

Lipshutz, BH ^{[1
]}

Chrisman, W ^{[1
]}

Noson, K ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 624卷 / 1-2期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

cooper hydride; hydrosilylation; silyl ethers; selective reductions;

D O I：

10.1016/S0022-328X(00)00903-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Exposure of an aldehyde or ketone to less than or equal to 5 mol% (in copper) of Stryker's reagent [Ph3P(CuH)](6) in the presence of one of several silanes affords the corresponding protected alcohol in high yields. Aldehydes can be cleanly reduced in the presence of ketones. (C) 2001 Elsevier Science B.V, AH rights reserved.

引用

页码：367 / 371

页数：5