Graphene Oxide Framework Materials: Theoretical Predictions and Experimental Results

被引:302
作者
Burress, Jacob W. [1 ]
Gadipelli, Srinivas [1 ,2 ]
Ford, Jamie [1 ,2 ]
Simmons, Jason M. [1 ]
Zhou, Wei [1 ,3 ]
Yildirim, Taner [1 ,2 ]
机构
[1] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA
[2] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[3] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA
关键词
boronic acids; carbon dioxide capture; graphene oxide; hydrogen storage; nanomaterials; ORGANIC FRAMEWORKS; HYDROGEN STORAGE; ADSORPTION;
D O I
10.1002/anie.201003328
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A promising storage medium for hydrogen and other gases is a graphene oxide framework (GOF) that consists of layers of GO connected by benzene-1,4- diboronic acid (B14DBA) pillars (see picture). Theoretical predictions and the initial experimental results are presented for this cheap and environmentally friendly building block for nanoporous materials with better gas adsorption properties. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:8902 / 8904
页数:3
相关论文
共 15 条
[1]   Hydrogen storage in engineered carbon nanospaces [J].
Burress, Jacob ;
Kraus, Michael ;
Beckner, Matt ;
Cepel, Raina ;
Suppes, Galen ;
Wexler, Carlos ;
Pfeifer, Peter .
NANOTECHNOLOGY, 2009, 20 (20)
[2]   Porous, crystalline, covalent organic frameworks [J].
Côté, AP ;
Benin, AI ;
Ockwig, NW ;
O'Keeffe, M ;
Matzger, AJ ;
Yaghi, OM .
SCIENCE, 2005, 310 (5751) :1166-1170
[3]   Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal-Organic Framework Functionalized with Ethylenediamine [J].
Demessence, Aude ;
D'Alessandro, Deanna M. ;
Foo, Maw Lin ;
Long, Jeffrey R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8784-+
[4]   Pillared Graphene: A New 3-D Network Nanostructure for Enhanced Hydrogen Storage [J].
Dimitrakakis, Georgios K. ;
Tylianakis, Emmanuel ;
Froudakis, George E. .
NANO LETTERS, 2008, 8 (10) :3166-3170
[5]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[6]  
Frenkel D., 2002, UNDERSTANDING MOL SI, V2nd edn
[7]   Intercalation and stitching of graphite oxide with diaminoalkanes [J].
Herrera-Alonso, Margarita ;
Abdala, Ahmed A. ;
McAllister, Michael J. ;
Aksay, Ilhan A. ;
Prud'homme, Robert K. .
LANGMUIR, 2007, 23 (21) :10644-10649
[8]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[9]   Nanoengineered Carbon Scaffolds for Hydrogen Storage [J].
Leonard, Ashley D. ;
Hudson, Jared L. ;
Fan, Hua ;
Booker, Richard ;
Simpson, Lin J. ;
O'Neill, Kevin J. ;
Parilla, Philip A. ;
Heben, Michael J. ;
Pasquali, Matteo ;
Kittrell, Carter ;
Tour, James M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (02) :723-728
[10]   Gas Adsorption Study on Mesoporous Metal-Organic Framework UMCM-1 [J].
Mu, Bin ;
Schoenecker, Paul M. ;
Walton, Krista S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (14) :6464-6471