Electroless deposition of zinc oxide on pincushion films prepared by self-organization

被引:16
作者
Hirai, Yuji
Yabu, Hiroshi
Shimomura, Masatsugu
机构
[1] Tohoku Univ, IMRAM, Aoba Ku, Sendai, Miyagi 9808577, Japan
[2] Hokkaido Univ, Grad Sch Sci, Kita Ku N10W8, Sapporo, Hokkaido, Japan
[3] RIKEN, Frontier Res Syst, Inst Phys & Chem Res, Wako, Saitama 35101, Japan
[4] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama, Japan
关键词
self-organization; zinc oxide; electroless deposition; microporous films;
D O I
10.1016/j.colsurfa.2007.04.117
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This report describes the electroless deposition of zinc oxide on pincushion-like polymer structures prepared by self-organization. By using condensed water droplet arrays as templates, a honeycomb-pattemed film was formed after evaporation of solvent and template water droplets from casting polymer solution. Well-ordered pincushion structures were prepared by peeling off the top layer of the honeycomb-pattemed film. Thin catalytic gold layer was sputtered onto the pincushion film of polystyrene and amphiphilic copolymer, and the gold-coated pincushion film was dipped in an aqueous solution containing zinc ion and reducer. The scanning electron microscopy and X-ray photoelectron spectroscopy revealed that zinc oxide layer was formed on the gold-coated pincushion film. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:312 / 315
页数:4
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