Temperature-promoted electrodeposition on thiolate-modified electrodes

被引：17

作者：

Cavalleri, O ^{[1
]}

Kind, H ^{[1
]}

Bittner, AM ^{[1
]}

Kern, K ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Dept Phys, Inst Expt Phys, CH-1015 Lausanne, Switzerland

来源：

LANGMUIR | 1998年 / 14卷 / 25期

关键词：

D O I：

10.1021/la980210d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The influence of temperature on the electrodeposition of copper on alkanethiolate-covered Au(lll) was studied by means of cyclic voltammetry and in situ scanning tunneling microscopy (STM) in the temperature range from 300 to 345 K. We show that thermally induced defects allow for copper electrodeposition to occur much faster than at 300 K. Only at elevated temperatures can smooth copper layers be grown on the thiolated electrodes, independent of the thiolate chain length. The layerwise growth is mediated by a surfactant-libe action of the thiolate.

引用

页码：7292 / 7297

页数：6

共 42 条

[21] COPPER ADLAYER FORMATION ON AU(111) FROM SULFURIC-ACID ELECTROLYTE [J].

GREEN, MP ;

HANSON, KJ .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1992, 10 (05) :3012-3018

[22] STRAIN DRIVEN FCC-BCT PHASE-TRANSITION OF PSEUDOMORPHIC CU FILMS ON PD(100) [J].

HAHN, E ;

KAMPSHOFF, E ;

WALCHLI, N ;

KERN, K .

PHYSICAL REVIEW LETTERS, 1995, 74 (10) :1803-1806

[23]

HAISS W, 1994, THESIS TU BERLIN GER

[24] OBSERVATIONS OF THE CU(1X1) ADLAYER ON AU(111) IN A SULFURIC-ACID-SOLUTION USING ATOMIC-FORCE MICROSCOPY [J].

IKEMIYA, N ;

MIYAOKA, S ;

HARA, S .

SURFACE SCIENCE, 1994, 311 (1-2) :L641-L648

[25] CHEMICAL AND PHYSICAL INTERACTIONS AT METAL SELF-ASSEMBLED ORGANIC MONOLAYER INTERFACES [J].

JUNG, DR ;

CZANDERNA, AW .

CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES, 1994, 19 (01) :1-54

[26] CONFORMATIONAL DISORDER IN CRYSTALLINE N-ALKANES PRIOR TO MELTING [J].

KIM, YS ;

STRAUSS, HL ;

SNYDER, RG .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (21) :7520-7526

[27]

KOLB DM, 1997, MATER RES SOC S P, V451, P9

[28] ATOMIC-STRUCTURE OF ORDERED COPPER ADLAYERS ON SINGLE-CRYSTALLINE GOLD ELECTRODES [J].

MAGNUSSEN, OM ;

HOTLOS, J ;

BETTEL, G ;

KOLB, DM ;

BEHM, RJ .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1991, 9 (02) :969-975

[29] MOBILITY OF THE ALKANETHIOL GOLD(111) INTERFACE STUDIED BY SCANNING PROBE MICROSCOPY [J].

MCCARLEY, RL ;

DUNAWAY, DJ ;

WILLICUT, RJ .

LANGMUIR, 1993, 9 (11) :2775-2777

[30] CUCL ADLAYER FORMATION AND CL INDUCED SURFACE ALLOYING - AN IN-SITU STM STUDY ON CU UNDERPOTENTIAL DEPOSITION ON AU(110) ELECTRODE SURFACES [J].

MOLLER, F ;

MAGNUSSEN, OM ;

BEHM, RJ .

ELECTROCHIMICA ACTA, 1995, 40 (10) :1259-1265

← 1 2 3 4 5 →