Highly active silica gel-supported metathesis (pre) catalysts

被引:48
作者
Fischer, D [1 ]
Blechert, S [1 ]
机构
[1] Tech Univ Berlin, Inst Organ Chem, D-106230 Berlin, Germany
关键词
alkenes; immobilization; metathesis; ruthenium; silica gel; supported catalysts;
D O I
10.1002/adsc.200505106
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Highly active Hoveyda-Grubbs and Hoveyda-Blechert type (pre)catalysts, immobilized on silica gel, are presented. These (pre)catalysts are synthesized in a few steps from readily available precursors and demonstrate high activity in a number of test metathesis reactions. The catalyst is easily separated by simple filtration of the non-swelling material.
引用
收藏
页码:1329 / 1332
页数:4
相关论文
共 35 条
[1]  
BLUMEL J, 1995, J AM CHEM SOC, V117, P2112
[2]   Recent advances in the synthesis of supported metathesis catalysts [J].
Buchmeiser, MR .
NEW JOURNAL OF CHEMISTRY, 2004, 28 (05) :549-557
[3]   An easily assembled highly active ruthenium initiator for olefin metathesis [J].
Buschmann, N ;
Wakamatsu, H ;
Blechert, S .
SYNLETT, 2004, (04) :667-670
[4]   An efficient method for removal of ruthenium byproducts from olefin metathesis reactions [J].
Cho, JH ;
Kim, BM .
ORGANIC LETTERS, 2003, 5 (04) :531-533
[5]  
Connon S. J., 2002, ANGEW CHEM, V114, P3989
[6]   Practical olefin metathesis in protic media under an air atmosphere [J].
Connon, SJ ;
Rivard, M ;
Zaja, M ;
Blechert, S .
ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (05) :572-575
[7]  
Connon SJ, 2002, ANGEW CHEM INT EDIT, V41, P3835, DOI 10.1002/1521-3773(20021018)41:20<3835::AID-ANIE3835>3.0.CO
[8]  
2-4
[9]   A solid-supported phosphine-free ruthenium alkylidene for olefin metathesis in methanol and water [J].
Connon, SJ ;
Blechert, S .
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2002, 12 (14) :1873-1876
[10]   A highly efficient olefin metathesis initiator: improved synthesis and reactivity studies [J].
Dunne, AM ;
Mix, S ;
Blechert, S .
TETRAHEDRON LETTERS, 2003, 44 (13) :2733-2736