Coordination chemistry of phosphole ligands:: From supramolecular assemblies to OLEDs

被引：32

作者：

Hissler, Muriel ^{[1
]}

Lescop, Christophe ^{[1
]}

Reau, Regis ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR Sci Chim 6226, F-35042 Rennes, France

来源：

COMPTES RENDUS CHIMIE | 2008年 / 11卷 / 6-7期

关键词：

phosphole; bridging phosphane; pi-conjugated systems; organic light emitting diodes; non-linear optics; supramolecular assemblies;

D O I：

10.1016/j.crci.2008.01.010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and properties of organophosphorus pi-conjugated chromophores incorporating metallic ions are described. Their optical and electrochemical properties depend on the metal centre linked to the organophosphorus atom. Moreover, the introduction of metallic ions induces a control of the supramolecular organization of the organophosphorus pi-conjugated systems. The specific properties of these complexes make them valuable materials for organic light-emitting diodes and interesting building blocks for the tailoring of novel NLO-phores.

引用

页码：628 / 640

页数：13

共 131 条

[1] Large molecular hyperpolarizabilities. Quantitative analysis of aromaticity and auxiliary donor-acceptor effects [J].

Albert, IDL ;

Marks, TJ ;

Ratner, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (28) :6575-6582

[2]

[Anonymous], 1998, ELECT MAT OLIGOMER A

[3]

[Anonymous], COMPREHENSIVE HETERO

[4] High-efficiency fluorescent organic light-emitting devices using a phosphorescent sensitizer [J].

Baldo, MA ;

Thompson, ME ;

Forrest, SR .

NATURE, 2000, 403 (6771) :750-753

[5] Luminescent and redox-active polynuclear transition metal complexes [J].

Balzani, V ;

Juris, A ;

Venturi, M ;

Campagna, S ;

Serroni, S .

CHEMICAL REVIEWS, 1996, 96 (02) :759-833

[6] RIGID ROD-LIKE DINUCLEAR RU(II) OS(II) TERPYRIDINE-TYPE COMPLEXES - ELECTROCHEMICAL-BEHAVIOR, ABSORPTION-SPECTRA, LUMINESCENCE PROPERTIES, AND ELECTRONIC-ENERGY TRANSFER THROUGH PHENYLENE BRIDGES [J].

BARIGELLETTI, F ;

FLAMIGNI, L ;

BALZANI, V ;

COLLIN, JP ;

SAUVAGE, JP ;

SOUR, A ;

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) :7692-7699

[7] A 1ST STEP TOWARD THE PHOSPHORUS ANALOGS OF POLYTHIOPHENES [J].

BEVIERRE, MO ;

MERCIER, F ;

RICARD, L ;

MATHEY, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (06) :655-657

[8]

BEVIERRE MO, 1991, NEW J CHEM, V15, P545

[9] Alternating copolymerization of carbon monoxide and olefins by single-site metal catalysis [J].

Bianchini, C ;

Meli, A .

COORDINATION CHEMISTRY REVIEWS, 2002, 225 (1-2) :35-66

[10]

Braunstein P, 2001, ANGEW CHEM INT EDIT, V40, P2427, DOI 10.1002/1521-3773(20010702)40:13<2427::AID-ANIE2427>3.0.CO

← 1 2 3 4 5 6 7 8 9 10 →