A dynamic microporous metal-organic framework with BCT zeolite topology: Construction, structure, and adsorption Behavior

被引:55
作者
Hu, Sheng
Zhang, Jie-Peng
Li, Hao-Xiang
Tong, Ming-Liang [1 ]
Chen, Xiao-Ming
Kitagawat, Susumu
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
关键词
D O I
10.1021/cg070602v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new microporous metal-organic framework (MOF) material [N-4(dpa)(4)(PYZ)(4)(H2O)(8)] center dot 11H(2)O (1) with BCT zeolite topology has been hydrothermally synthesized. The framework components undergo dynamic structural transformation in response to removal and rebinding of the suitable guest molecules.
引用
收藏
页码:2286 / 2289
页数:4
相关论文
共 37 条
  • [1] Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO
  • [2] 2-Y
  • [3] Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
  • [4] 2-Z
  • [5] Design, chirality, and flexibility in nanoporous molecule-based materials
    Bradshaw, D
    Claridge, JB
    Cussen, EJ
    Prior, TJ
    Rosseinsky, MJ
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) : 273 - 282
  • [6] Flexible sorption and transformation behavior in a microporous metal-organic framework
    Cussen, EJ
    Claridge, JB
    Rosseinsky, MJ
    Kepert, CJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (32) : 9574 - 9581
  • [7] MIL-103, a 3-D lanthanide-based metal organic framework with large one-dimensional tunnels and a high surface area
    Devic, T
    Serre, C
    Audebrand, N
    Marrot, J
    Férey, G
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (37) : 12788 - 12789
  • [8] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
    Eddaoudi, M
    Kim, J
    Rosi, N
    Vodak, D
    Wachter, J
    O'Keeffe, M
    Yaghi, OM
    [J]. SCIENCE, 2002, 295 (5554) : 469 - 472
  • [9] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks
    Eddaoudi, M
    Moler, DB
    Li, HL
    Chen, BL
    Reineke, TM
    O'Keeffe, M
    Yaghi, OM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 319 - 330
  • [10] Fang QR, 2006, DALTON T, P2399, DOI 10.1039/b517400g