Self-assembled chiral terpyridine ruthenium complexes

被引:9
作者
El-ghayoury, A
Hofmeier, H
Schenning, APHJ
Schubert, US
机构
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands
[3] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
关键词
CD spectroscopy; chirality; metal complex; self-organization; terpyridine;
D O I
10.1016/j.tetlet.2003.10.187
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A rigid terpyridine ligand containing chiral alkyl chains has been synthesized, characterized and subsequently complexed with ruthenium(II) ions. The product was characterized by MALDI-TOF-MS, UV-vis and NMR. Circular dichroism showed the appearance of extended helical columnar aggregates. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:261 / 264
页数:4
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