Sorption-desorption behavior of bispyrazolato-copper(II) 1D coordination polymers

被引:179
作者
Cingolani, A
Galli, S
Masciocchi, N
Pandolfo, L
Pettinari, C
Sironi, A
机构
[1] Univ Insubria, Dipartimento Sci Chim & Ambientali, I-22100 Como, Italy
[2] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, MC, Italy
[3] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy
[4] Univ Milan, Dipartimenot Chim Structt & Stereochim Inorgan, I-20123 Milan, Italy
关键词
D O I
10.1021/ja050856+
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new polycrystalline vapochromic polymorph of the one-dimensional copper bispyrazolate polymer reversibly and selectively absorbs a number of small molecules; the crystal structures of the anhydrous and fully hydrated species, determined by powder diffraction methods, are markedly different despite their simple, fast, and reversible interconversion. Copyright © 2005 American Chemical Society.
引用
收藏
页码:6144 / 6145
页数:2
相关论文
共 16 条
  • [1] Mineralomimetic sodalite- and muscovite-type coordination frameworks. Dynamic crystal-to-crystal interconversion processes sensitive to ion pair recognition
    Barea, E
    Navarro, JAR
    Salas, JM
    Masciocchi, N
    Galli, S
    Sironi, A
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) : 3014 - 3015
  • [2] Crystal engineering - nucleation, the key step
    Davey, RJ
    Allen, K
    Blagden, N
    Cross, WI
    Lieberman, HF
    Quayle, MJ
    Righini, S
    Seton, L
    Tiddy, GJT
    [J]. CRYSTENGCOMM, 2002, 4 : 257 - 264
  • [3] METAL PYRAZOLATE POLYMERS .2. SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF [CU(4-CL PYRAZOLATE)2)X, (CU(4-BR PYRAZOLATE)2)X, (CU(4-ME PYRAZOLATE)2)X, (CU(4-H PYRAZOLATE)2)X POLYMERS
    EHLERT, MK
    RETTIG, SJ
    STORR, A
    THOMPSON, RC
    TROTTER, J
    [J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1991, 69 (03): : 432 - 439
  • [4] A detailed study of the vapochromic behavior of {Tl[Au(C6Cl5)2]}n
    Fernández, EJ
    López-De-Luzuriaga, JM
    Monge, M
    Montiel, M
    Olmos, ME
    Pérez, J
    Laguna, A
    Mendizabal, F
    Mohamed, AA
    Fackler, JP
    [J]. INORGANIC CHEMISTRY, 2004, 43 (12) : 3573 - 3581
  • [5] Non-classical Fe-II spin-crossover behaviour leading to an unprecedented extremely large apparent thermal hysteresis of 270 K: Application for displays
    Garcia, Y
    vanKoningsbruggen, PJ
    Codjovi, E
    Lapouyade, R
    Kahn, O
    Rabardel, L
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (06) : 857 - 858
  • [6] GASPARAC R, 2000, EFC BOOK SERIES, V28, P20
  • [7] Spin crossover phenomena in Fe(II) complexes
    Gütlich, P
    Garcia, Y
    Goodwin, HA
    [J]. CHEMICAL SOCIETY REVIEWS, 2000, 29 (06) : 419 - 427
  • [8] SPIN TRANSITION MOLECULAR MATERIALS FOR DISPLAYS AND DATA RECORDING
    KAHN, O
    KROBER, J
    JAY, C
    [J]. ADVANCED MATERIALS, 1992, 4 (11) : 718 - 728
  • [9] LaMonica G, 1997, PROG INORG CHEM, V46, P151
  • [10] Metal pyrazolato complexes. Synthesis, characterization, and X-ray powder diffraction studies of group 12 coordination polymers
    Masciocchi, N
    Ardizzoia, GA
    Maspero, A
    LaMonica, G
    Sironi, A
    [J]. INORGANIC CHEMISTRY, 1999, 38 (16) : 3657 - 3664