Alternatives to phosgene and carbon monoxide: Synthesis of symmetric urea derivatives with carbon dioxide in ionic liquids

被引：248

作者：

Shi, F ^{[1
]}

Deng, YQ ^{[1
]}

SiMa, TL ^{[1
]}

Peng, JJ ^{[1
]}

Gu, YL ^{[1
]}

Qiao, BT ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 28期

关键词：

amines; carbon dioxide; carbonylation; green chemistry; ionic liquids;

D O I：

10.1002/anie.200351098

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simple, clean, safe, reproducible, and practical describes the synthesis of disubstituted urea derivatives, which are effectively synthesized from amines and carbon dioxide with a CsOH/ionic-liquid catalyst system. The products are easily separated and the catalytic system can be reused without deactivation (see picture).

引用

页码：3257 / 3260

页数：4

共 57 条

[51]

Wasserscheid P., 2000, ANGEW CHEM INT EDIT, V112, P3926, DOI DOI 10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO

[52]

2-5

[53] SUBTLE BALANCE BETWEEN VARIOUS PHENANTHROLINE LIGANDS AND ANIONS IN THE PALLADIUM-CATALYZED REDUCTIVE CARBONYLATION OF NITROBENZENE [J].