Highly efficient synthesis of Fe-containing mesoporous materials by using semi-fluorinated surfactant and their high activities in Friedel-Crafts alkylations

被引：24

作者：

Du, Yunchen

Liu, Sen

Ji, Yanyan

Zhang, Yonglai

Liu, Fujian

Gao, Qian

Xiao, Feng-Shou ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China

来源：

CATALYSIS TODAY | 2008年 / 131卷 / 1-4期

基金：

中国国家自然科学基金;

关键词：

Fe-containing mesoporous materials; Fe-JLU-15; benzylation; semi-fluorinated surfactant;

D O I：

10.1016/j.cattod.2007.10.021

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Fe-containing mesoporous materials (Fe-JLU-15) with various Si/Fe ratios (47-112) have been successfully synthesized by using semi-fluorinated surfactant of FSO-100 as a template. XRD, N-2 isotherm, and TEM techniques indicate that these samples have worm-like mesostructure with uniform pore size. UV-vis and ESR spectra suggest that Fe species in Fe-JLU-15 are mainly tetrahedrally coordinated. Interestingly, compared with Fe-SBA-15, the efficiency of incorporation of Fe species into Fe-JLU-15 is relatively high. Very importantly, catalytic data in benzylation of aromatic compounds such as benzene, toluene, and ethylbenzene with benzyl chloride shows that Fe-JLU-15 samples are very active and recycle catalysts. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：70 / 75

页数：6

共 28 条

[1] Benzylation of benzene by benzyl chloride over iron mesoporous molecular sieves materials [J].