Trinuclear double helicates of iron(II) and nickel(II): Self-assembly and resolution into helical enantiomers

被引:71
作者
Hasenknopf, B [1 ]
Lehn, JM [1 ]
机构
[1] UNIV STRASBOURG 1,INST LE BEL,F-67000 STRASBOURG,FRANCE
关键词
D O I
10.1002/hlca.19960790615
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of the linear tris[terpyridine] 1 with three tridentate binding sites is described. The reaction with metal ions of octahedral coordination geometry, such as Fe-II or Ni-II, leads to the self-assembly of trinuclear complexes [M(3)(1)(2)](6+), which display properties in agreement with a double helical structure. The trinuclear iron(II) helicate has been resolved into its enantiomers.
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页码:1643 / 1650
页数:8
相关论文
共 29 条
[1]   SELF-ASSEMBLY OF HOMOCHIRAL DOUBLE HELIX AND SIDE-BY-SIDE HELIX CONFORMERS OF A DOUBLE-STRANDED DISILVER(I)-TETRA(TERTIARY PHOSPHINE) COMPLEX [J].
AIREY, AL ;
SWIEGERS, GF ;
WILLIS, AC ;
WILD, SB .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (06) :695-696
[2]   CRYSTAL-STRUCTURE OF BIS(2,2'-6',2''-TERPYRIDINE)IRON(II) BIS(PERCHLORATE) HYDRATE [J].
BAKER, AT ;
GOODWIN, HA .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1985, 38 (01) :207-214
[3]  
CAHN RS, 1966, ANGEW CHEM INT EDIT, V5, P515
[4]   THE SYNTHESIS OF CERTAIN SUBSTITUTED 2,2'-BIPYRIDYLS [J].
CASE, FH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (12) :2574-2577
[5]   SYNTHESIS, STRUCTURE AND RESOLUTION OF A DINUCLEAR CO-III TRIPLE-HELIX [J].
CHARBONNIERE, LJ ;
BERNARDINELLI, G ;
PIGUET, C ;
SARGESON, AM ;
WILLIAMS, AF .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (12) :1419-1420
[6]   HIGHER OLIGOPYRIDINES AS A STRUCTURAL MOTIF IN METALLOSUPRAMOLECULAR CHEMISTRY [J].
CONSTABLE, EC .
PROGRESS IN INORGANIC CHEMISTRY, VOL 42, 1994, 42 :67-138
[7]  
CRANE JD, 1992, NEW J CHEM, V16, P649
[8]   PREPARATION OF TRICARBONYL(ETA-6-PYRIDINE)CHROMIUM(0) COMPLEXES [J].
DAVIES, SG ;
SHIPTON, MR .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (03) :501-507
[9]   SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A STEREOSPECIFIC DINUCLEAR GALLIUM TRIPLE-HELIX - USE OF THE TRANSINFLUENCE IN METAL-ASSISTED SELF-ASSEMBLY [J].
ENEMARK, EJ ;
STACK, TDP .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (09) :996-998
[10]   Self-assembly of a heteroduplex helicate from two different ligand strands and Cu(II) cations [J].
Hasenknopf, B ;
Lehn, JM ;
Baum, G ;
Fenske, D .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1996, 93 (04) :1397-1400